Showing 8 results for rastegari
Arabi H., Rastegari S., Mohammad-Sadeghi B.,
Volume 1, Issue 1 (Oct 2004)
Abstract
In this research, effects of changes in aluminizing conditions on microstructure of Pt - aluminide coating applied oil a Ni - base superalloy GTD -111, has been studied. A thin layer (i.e.68,#mm ) of Pt was electroplated onto the surface of the .samples, and then they were aluminized by pack cementation technique under various conditions of time, temperature, rate of heating and pack powder compositions In addition, by application of a thin Ni layer on the substrate before applying Pt, the source of nickel available for diffusing into Pt layer during aluminizing process enhanced and the need for an extra heat treatment cycle before aluminizing process was practically omitted. Addition of a nickel layer, also prevented scaling of Pt layer during its electroplating and aluminizing processes that helps enhancement of cohesiveness of the coated layers.The general microstructure of the coating consisted of four layers, which are PtA12layer internal diffusion layer external diffusion layer and interdiffusion zone. The structure of each layer has been studied by optical and scanning electron microscopes as well as XRD technique.The results show the presence of the original Pt - electroplated layer had no effect on the thicknesses of the coating layers, but higher aluminizing time and temperature had increased the thicknesses of interdiffusion and internally diffused layers. In addition, at high temperature, aluminizing with a lower heating rate caused an increase in the thickness of internal diffusion layer. Aluminizing with a lower heating rate at high temperature (more than 900°C) had increased the thickness of interdiffusion laver Attempt has been made to justify , the changes occurred in microstructures and thick nesses of various coating layers as they exposed to different aluminizing conditions.
H. Aghajani, M. Soltanieh, F. Mahboubi, S. Rastegari and Kh. A. Nekouee,
Volume 6, Issue 1 (winter 2009 2009)
Abstract
Abstract: Formation of a hybrid coating by the use of plasma nitriding and hard chromium electroplating on the
surface of H11 hot work tool steel was investigated. Firstly, specimens were plasma nitrided at a temperature of 550
°C for 5 hours in an atmosphere of 25 vol. % H2: 75 vol. % N2. Secondly, electroplating was carried out in a solution
containing 250 g/L chromic acid and 2.5 g/L sulphuric acid for 1 hour at 60 °C temperature and 60 A/dm2 current
density. Thirdly, specimens were plasma nitrided at a temperature of 550 °C for 5 and 10 hours in an atmosphere of
25 vol. % H2: 75 vol. % N2. The obtained coatings have been compared in terms of composition and hardness. The
compositions of the coatings have been studied by X-ray diffraction analysis. The surface morphology and elemental
analysis was examined by using scanning electron microscopy. The improvement in hardness distribution after third
step is discussed in considering the forward and backward diffusion of nitrogen in the chromium interlayer. Also, the
formed phases in the hybrid coating were determined to be CrN+Cr2N+Cr+Fe2-3N+Fe4N.
H. Rafiee*,, S. Rastegari, H. Arabi, M. Mojaddami,
Volume 7, Issue 4 (Autumn 2010 2010)
Abstract
Abstract:
activity gas diffusion process has been investigated in this research. Effects of coating temperature and aluminum
concentration in powder mixture on formation mechanism were studied using optical and scanning electron
microscopes, EDS and X-ray diffraction (XRD) techniques. For this purpose two different packs containing 1 and 2
wt% aluminum powder, were used for coating the samples at two temperatures, 850ºC and 1050ºC. The ratio of Al to
activator was kept constant in both packs. By increasing the Al content in high activity powder mixture, the
concentration of diffused Al increased in the coating layers, and the thickness of coating increased. At 1050ºC as the
rate of diffused Al to the interdiffusion zone increased, this zone gradually transformed to outer coating phases. At
850ºC coating formed by inward diffusion of Al, but at 1050ºC it was initially formed by inward diffusion of Al followed
by outward diffusion of Ni.
Formation mechanism of an aluminide coating on a nickel base superalloy IN738LC via a single step high
H. Arabi, S. Rastegari, V. Ramezani, Z. Valefi,
Volume 10, Issue 2 (June 2013)
Abstract
The objectives of this research were to find an economical way of reducing porosities in the microstructure of coatings deposited by flame spraying technique on CK45 steel and also trying to increase their cohesive strength to the substrate, so that the overall wear properties of this type of coating can be improved. So several specimens from this steel coated with NiCrBSi powder under specific conditions were subjected to various furnace heat treatment at 1000, 1025, 1050, 1075 and 1100 °C, each for periods of 5, 10 and 15 minute before cooling them in air. Tribological properties of treated coatings were evaluated by pin on disc method. The results show the highest wear resistance and microhardness values observed in one of the sample was due to lower amount of porosity and higher amount of very fine Cr2Ni3B6 particles precipitated homogeneously throughout its microstructure during specific heat treatment.
M. Karimi Sahnesarayi, H. Sarpoolaky, S. Rastegari,
Volume 16, Issue 2 (June 2019)
Abstract
In this study nanosized TiO2coatings on the 316L stainless steel substrate were prepared by means of dip-coating technique in which thickness of the coating layer increased byrepeating the coating cycles in two different routes: (I) dipping and drying,respectively, were repeated one, three and five times and finally the dried coated sample was heat treated (single); (II) multiple heat treatment performed after each dipping and drying cycle, respectively.The structural, morphological and optical characterizations of coatings as well as thickness of coatings were systematically studied.The photocatalytic activity of the various TiO2 coatings was investigated based on the degradation of an aqueous solution of Methyl orange.Moreover, thecorrosion protective properties of coatings were evaluated in both dark and UV illumination conditions based on the obtained polarization curves. The results indicated 1.75 times improvement in photocatalytic reaction rate constant, a two orders of magnitude decrease in corrosion current density in dark condition and about 140 mV electrode potential reduction under UV illumination with optimum coating preparation procedure, repeating the cycle from dipping to heat treatment three times, than the sample prepared with one time coating and heat treatment since this procedure provided not only high thickness and defect-free coating but also transparent one.
R. Latifi, S. Rastegari, S. H. Razavi,
Volume 16, Issue 4 (December 2019)
Abstract
In the present study, Zirconium modified aluminide coating on the nickel-base superalloy IN-738LC was first created by high activity high temperature aluminizing based on the out-of-pack cementation method. Then, Zr coatings were applied to simple aluminide coatings by sputtering and heat treatment in order to study the effect of Zr on the coating microstructure and oxide spallation. Microstructural studies were conducted by using scanning electron microscopy (SEM), Energy Dispersive X-ray Spectrometry (EDS), and x-ray diffraction (XRD) microanalysis. The results indicated that zirconium modified aluminide coating, like aluminide coating, has a two-layer structure including a uniform outer layer of NiAl and an interdiffusion layer in which zirconium is in a form of solid solution in the coating. Furthermore, the 300nm Zr-coated NiAl demonstrated an excellent scale adhesion, a slow oxidation rate and lower amounts of some other elements such as Ti and Cr in its oxide layer leading to a pure aluminide oxide layer.
M. Ghasemian Safaei, Dr. S. Rastegari, R. Latifi,
Volume 17, Issue 2 (June 2020)
Abstract
In this study, Si-modified aluminide coating on nickel-base superalloy IN-738LC was prepared using a pack cementation method with various powder compositions at 1050 °C for 6 h. The cyclic oxidation test was conducted at 1000 °C followed by cooling at room temperature for 200 h and 20 cycles. The effect of powder composition and the way of cooling on the coatings microstructure and oxidation behavior were studied. Investigations carried out using a scanning electron microscope (SEM), EDS analysis, and XRD. Microstructural observations revealed that the coating thickness of 293 and 274 µm was achieved in the case of using pure Al and Si powder and alloyed Al-20wt.%Si one in the packed mixture, respectively. It was also found that utilizing pure Al and Si powder with NH4Cl as an activator in the pack led to the formation of silicide coating, owing to the higher diffusion of Si, which showed superior cyclic oxidation performance.
Mohammad Derakhshani, Saeed Rastegari, Ali Ghaffarinejad,
Volume 21, Issue 2 (June 2024)
Abstract
In this research, a nickel-tungsten coating as a catalyst for hydrogen evolution reaction (HER) with different current densities was synthesized and the resulting electrocatalytic properties and morphology were assessed. Linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), and chronoamperometry in 1 M NaOH were used to evaluate the electrocatalytic activity for HER. By increasing the current density of electrodeposition up to 500 mA/cm2, a columnar morphology was observed. The cyclic voltammetry test (CV) revealed that when the plating current density increases, Cdl has increased from 248 to 1310 µF/cm2 and the active surface area increases 5 times. The results showed that by modifying the coating morphology, the current density of the hydrogen evolution increased up to two times.
