Iranian Journal of Materials Science and Engineering

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A new process for recovering scheelite ores comprises producing a concentrate from the ore, then leaching the concentrate with H_2SO_4 in the presence of H_3PO_4 and Na Cl at atmosphericpressure are discussed. Finely purification of the product will be described. The amounts of dissolution of tungsten in acid depend on the parameters such as time, temperature, type and concentration of acid and stilt as well as solid-liquid reaction. These factors were optimized for the result and described in details.

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Abstract: Production of titanium aluminides in TiO2-Al-Ca system has been investigated. For this purpose, different compositions of raw materials were studied in a special reaction vessel. In a special case, the non-completed reaction of TiO2 with Al and Ca resulted in the production of granulates of titanium aluminides especially Ti3Al and other Ti – Al phases as the metallic product and Ca12Al14O33 as the non-metallic product. Remelting of metallic granulates led to production of TiAl ingot.

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Abstract:

materials can be fabricated by sintering of W-Cu composite powders. In this research W-20%wt Cu composite powders

was synthesized via a co-precipitation method. Precipitate obtained from a mixture of copper nitrate and ammonium

paratungstate (APT) in distilled water contained W-Cu compounds. This precipitate was washed, dried and calcined

at 550

of dried precipitate powder was determined by thermogravimetry (TG), differential thermal analysis (DTA) and X-ray

diffraction (XRD). The sintering of the reduced powders was investigated as a function of temperature. Relative density

of more than 98% obtained for the powders sintered at 1200

close to theoretical calculations. The hardness of the sintered powders was 320 Vickers.

W-Cu composites are widely used as contacts, heat sinks and electro discharge electrodes. These kinds of°C in air and then reduced in H2 atmosphere in order to convert to W-Cu powders. The calcination temperature°C . The corresponding electrical conductivity was too

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Abstract: The aim of the present investigation is to study the physical and mechanical characteristics of dental-filling spherical high-copper and silver amalgams and to compare them with a common high-copper domestic unicompositional amalgam. In this study, cylindrical specimens were mechanically condensed according to the ISO 1559:1986 Standard in order to measure the compressive strength, Vickers hardness, static creep and dimensional change on setting. Adding more silver to the amalgam increased its compressive strength, creep resistance and reduced mercury vapor. After 1, 24 and 168h of amalgamation and Modulus of elasticity of specimen S1, the mean hardness and compressive fracture strength were significantly lower than those of . No significant differences were identified for the two alloys in the creep and dimensional changes on setting. It can be concluded that as far as the mechanical properties or corrosion resistance is concerned, the amalgam should be comprised of at least one spherical alloy.

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Abstract: The supersolidus liquid phase sintering characteristics of commercial 2024 pre-alloyed powder was studied at different sintering conditions. Pre-alloyed 2024 aluminum alloy powder was produced via air atomizing process with particle size of less than 100 µm. The solidus and liquidus temperatures of the produced alloy were determined using differential thermal analysis (DTA). The sintering process was performed at various temperatures ranging from the solidus to liquidus temperatures in dry N2 gas atmosphere for 30 min in a tube furnace. The maximum density of the 2024 aluminum alloy was obtained at 610ºC which yields parts with a relative density of 98.8% of the theoretical density. The density of the sintered samples increased to the maximum 99.3% of the theoretical density with the addition of 0.1 wt. %Sn powder to the 2024 pre-alloyed powder. The maximum density was obtained at 15% liquid volume fraction for both powder mixtures.

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In this research, the effect of annealing and aging temperature as well as the effect of quenching media on the microstructure, hardness and dry sliding wear behavior of Ti-6Al-4V alloy has been studied. Cylindrical samples with the diameter of 10 mm and the height of 20mm were solutionized at 930˚C and 1060˚C for 600 seconds and then were quenched in the cold water and in the air. The samples were aged at different temperature of 480˚C, 550˚C and 610˚C for 360 s to increase the hardness. Heat treated samples were tested using standard pin-on-disc test machine at the applied loads of 100, 150 and 200 N. Microstructural investigations using scanning electron microscope revealed that for the samples solutionized at 930˚C and quenched in the water, the microstructure is composed of primary α and high volume fraction of martensitic α΄ phase with fine precipitated of β between martensitic lathes. In the case of air cooled samples, transformed β has also been  appeared in the vicinity of primary α. For the samples solutionized at 1060˚C and quenched in the water, fully martensitic micro structure with fine β precipitates was observed. For the sample solutionized at 1060˚C and air quenched, plate like α and lamellar grain boundary β were detected. The maximum hardness value relates to the sample solutionized at 1060˚C and quenched in water which is equal to 433 HV. Different wear mechanisms, including oxidative wear, scratch, and delamination occurred at the worn surfaces at different applied loads. For the samples quenched in the water, the oxidative wear mechanism governing at low applied load and oxide debris was observed as separate or compacted particles which formed in the contact between pin and steel counter face detached from the sample. At higher applied loads, delamination and scratch mechanism was also observed and metallic plate like debris was detached from the sample. Mechanically mixed layer (MML) was formed on the surface of the pin at high applied loads and for the samples with low hardness value adhesion marks were also revealed on the steel disc. The minimum weight loss in the wear test is related to the sample quenched from the 1060ºC in the cold water and aged at 550 ºC .  

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In the present study, Zirconium modified aluminide coating on the nickel-base superalloy IN-738LC was first created by high activity high temperature aluminizing based on the out-of-pack cementation method. Then, Zr coatings were applied to simple aluminide coatings by sputtering and heat treatment in order to study the effect of Zr on the coating microstructure and oxide spallation. Microstructural studies were conducted by using scanning electron microscopy (SEM), Energy Dispersive X-ray Spectrometry (EDS), and x-ray diffraction (XRD) microanalysis. The results indicated that zirconium modified aluminide coating, like aluminide coating, has a two-layer structure including a uniform outer layer of NiAl and an interdiffusion layer in which zirconium is in a form of solid solution in the coating. Furthermore, the 300nm Zr-coated NiAl demonstrated an excellent scale adhesion, a slow oxidation rate and lower amounts of some other elements such as Ti and Cr in its oxide layer leading to a pure aluminide oxide layer. 

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Niobium addition is an appropriate approach for improvement of superalloy’s operation. The purpose of this study is twofold: (1) to investigate on the η and γ^/ phase precipitations along with (2) to identify the high-temperature tensile properties in A286 and Nb-A286, as a modified type. The heat treatment of both alloys was carried out in a two-stage aging procedure at 760°C for 16 h and 820°C for 2 to 30 hours, following characterized by optical and Scanning electron (SEM-EDS) microscopies, differential thermal analysis (DTA) and high temperature tensile tests. The results showed that niobium addition was increased the volume fraction of γ^/ phase, from 10.7% to 12%, decreased its size, from 94 to 71 nm, and rising the γ^/-dissolution temperature from 987°C to 1007°C. Moreover, the γ^/ to η phase transformation was sluggishly occurred in Nb-A286 due to more stable of γ^/ precipitations. Furthermore, the Nb-A286 alloy demonstrates higher mechanical properties than A286 one, approximately 100MPa improvement, which it was contributed to the much large volume fraction and finer size of more stabilized γ^/ phase.
 

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In this research, after pressing in a cylindrical mold, the AA 7075 alloy swarf was melted and cast in a wet sand mold. After rolling and cutting, sheets with two different thicknesses of 6 and 20 mm were obtained. The sheets after homogenization were solutionized at 485°C for 30 and 90 minutes, respectively, due to differences in thickness and thermal gradients. The solutionized samples were quenched in 3 polymer solutions containing 10, 30, and 50% Poly Alekylene Glycol. The results showed that melting, casting, rolling, and heat treatment of AA7075 alloy swarf similar properties to this alloy is achievable. Microstructural studies by optical microscopes (OM), Field Emission Scanning Electron Microscopy (FESEM), and X-ray diffraction (XRD) showed that by increasing the quenching rate after the solutionizing process, precipitation increases during aging. The tensile test results indicated that as the quench rate and internal energy increase, the diffusion driving force would increase the precipitation of alloying elements. Hence, this leads to an increase in hardness and reduction of its strain after aging.