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Highlights
1) Confined/unconfined crystallizations of P3HT/carbonic materials were investigated in DSC-crystallized nanostructures and solution-grown supramolecules.
2) Absorbance, structure details, fusion enthalpy and crystallinity were focused in two different crystallization environments.
3) The best results were recorded for CNT-g-PDDT/P3HT stem-leaf and rGO-g-PDDT/P3HT coarse-patched supramolecules.